[Dr. John W. Sibert, Associate Professor]
[Copper Cyclam Complex Crystal]    
[Department of Chemistry, The University of Texas at Dallas][Department of Chemistry at the University of Texas at Dallas]
Department of Chemistry
The University of Texas at Dallas
800 W Campbell Road
Richardson, TX 75080-3021

phone: (972) 883-2918
fax: (972) 883-2925
[Research] [Group] [Publications] [Presentations] [Classes]

Patents

Sibert, John W. "Wurster's Crown Ligands," U.S. Patent 6 262 258, 2001.

Sibert, John W. "Wurster's Crown Ligands," U.S. Patent 6 441 164, 2002.

Publications

Sibert, J. W.; Forshee, P. B.; Lynch, V. "Electron Transfer vs. Coordination Chemistry: Isomer-Specific Binding of Hg(II) by an ortho-Wurster's Thiacrown Ether," Inorg. Chem. 2006, 45, 6108-6110.

Forshee, P. B.; Sibert, J. W. "Sodium Amalgam: A Highly Efficient Reagent for the Detosylation of Azathiacrown Ethers," Synthesis 2006, 5, 756-758.

Sargent, A. L.; Mosley, B. J.; Sibert, J. W. "A Theoretical Investigation on the Wurster's Crown Analogue of 18-Crown-6," J. Phys. Chem. A 2006, 110, 3826-3837.

Sibert, J. W.; Hundt, G. R.; Sargent, A. L.; Lynch, V. "Wurster's crownophanes: an alternate topology for para-phenylenediamine-based macrocycles," Tetrahedron 2005, 61, 12350-12357.

Sibert, J. W.; Forshee, P. B.; Lynch, V. "Wurster's Thiacrown Ethers: Synthesis, Properties and Pt(II) Coordination Chemistry," Inorg. Chem. 2005, 44, 8602-8609.

Sibert, J. W.; Seyer, D. J.; Hundt, G. R. “meta-Wurster’s Crowns”: The Synthesis and Properties of meta-Phenylenediamine-based Macrocycles,” J. Supramol. Chem. 2002, 2, 335-342.

Sibert, J. W.; Forshee, P. B. "ortho-Wurster's Crowns: Synthesis and Properties of a Novel Phenylenediamine-Based Redox-Active Macrocyclic Ligand," Inorg. Chem. 2002, 41, 5928-5930.

Sibert, J. W.; Cory, A. H.; Cory, J. G. "Lipophilic Derivatives of Cyclam as New Inhibitors of Tumor Cell Growth," J. Chem. Soc., Chem. Commun. 2002, 154-155.

Lange, S. J., Sibert, J. W.; Barrett, A. G. M; Hoffman, B. M. "Synthesis and Coordination Chemistry of Unsymmetrical Tetraazaporphyrins Containing Single Oxathia- and Thia-Crown Substituents," Tetrahedron 2000, 56(38), 7371-7377.

Ehrlich, L. A.; Skrdla, P. J.; Jarrell, W. K.; Sibert, J. W.; Armstrong, N. R.; Saavedra, S. S.; Barrett, A. G. M.; Hoffman, B. M. "Preparation of Polyetherol-Appended Sulfur Porphyrazines and Investigations of Peripheral Metal Ion Binding in Polar Solvents," Inorg. Chem. 2000, 39, 3963-3969.

Book Review: Sibert, J. W. "Perspectives on Bioinorganic Chemistry. Volume 4," J. Am. Chem. Soc. 2000, 122, 5233.

Andersen, K.; Anderson, M., Anderson, O. P.; Baum, S.; Baumann, T. F.; Beall, L. S.; Broderick, W. E.; Cook, A. S.; Eichhorn, D. M.; Goldberg, D.; Hope, H.; Jarrell, W.; Lange, S. J.; McCubbin, Q. J.; Mani, N. S.; Miller, T.; Montalban, A. G.; Rodriguez-Morgade, M. S.; Lee, S.; Nie, H.; Olmstead, M. M.; Sabat, M.; Sibert, J. W.; Stern, C.; White, A. J. P.; Williams, D. B. G.; Williams, D. J.; Barrett, A. G. M.; Hoffman, B. M. "Star Porphyrazines and Related Multimetallic Macrocycles," J. Heterocyclic Chem. 1998, 35, 1013-1042.

Sibert, J. W.; Baumann, T. F.; Williams, D. J.; White, A. J. P.; Barrett, A. G. M.; Hoffman, B. M. "gemini-Porphyrazines: The Synthesis and Characterization of Metal-Capped cis- and trans-Porphyrazine Tetrathiolates," J. Am. Chem. Soc. 1996, 118, 10487-10493.

Baumann, T. F.; Nasir, M. S.; Sibert, J. W.; White, A. J. P.; Olmstead, M. M.; Williams, D. J.; Barrett, A. G. M.; Hoffman, B. M. "solitaire-Porphyrazines: Synthetic, Structural, and Spectroscopic Investigation of Complexes of the Novel Binucleating Norphthalocyanine-2,3-dithiolato Ligand," J. Am. Chem. Soc. 1996, 118, 10479-10486.

Weghorn, S. J.; Sessler, J. L.; Lynch, V.; Baumann, T. F.; Sibert, J. W. "Bis-[(m-chloro)copper(II)]Amethyrin: A Bimetallic Copper(II) Complex of an Expanded Porphyrin," Inorg. Chem. 1996, 35, 1089-1090.

Sibert, J. W.; Lange, S. J.; Stern, C. L.; Barrett, A. G. M.; Hoffman, B. M. "Octathioporphyrazine Crown Ethers. An Octanuclear Ag(I) Complex with Coordination in the meso Pocket," Angew. Chem. Int. Ed. Engl. 1995, 34, 2020-2022.

Lange, S. J.; Sibert, J. W.; Stern, C. L.; Barrett, A. G. M.; Hoffman, B. M. "Macrocyclic Dithiomaleonitrile Derivatives Containing Sulfur and Nitrogen Heteroatoms," Tetrahedron 1995, 51, 8175-8188.

Sibert, J. W.; Lange, S. J.; Williams, D. J.; Barrett, A. G. M.; Hoffman, B. M. "Heavy Metal Complexes of Oxa-Crowned Derivatives of Dithiomaleonitrile," Inorg. Chem. 1995, 34, 2300-2305.

Sibert, J. W.; Lange S. J.; Stern, C.; Hoffman, B. M.; Barrett, A. G. M. "Unusual Coordination of HgCl2 by a Mixed Oxathioether Crown," J. Chem. Soc., Chem. Commun. 1994, 1751-1752.

Baumann, T. F.; Sibert, J. W.; Olmstead, M. M.; Hoffman, B. M.; Barrett, A. G. M. "Solitaire Porphyrazines: X-ray Crystal Structure and Spectroscopy of [1,1'Bis(diphenylphosphino)-ferrocene]-[(norphthalocyanine)dithiolato]palladium(II)," J. Am. Chem. Soc. 1994, 116, 3339-3340.

Sessler, J. L.; Sibert, J. W.; Lynch, V. "Bulky Substituent Effects on the Iron(III) Complexation of 1,4,7-triazacyclononane," Inorg. Chim. Acta 1994, 216, 89-95.

Sessler, J. L.; Sibert, J. W. "On the Synthesis of Unsymmetrical Bis(Macrocyclic) Ligands," Tetrahedron 1993, 49, 8727-8738.

Sessler, J. L.; Sibert, J. W.; Burrell, A. K.; Lynch, V.; Markert, J. T.; Wooten, C. L. "Oxo-Bridged Iron Clusters. Synthesis of 1,3-Bis(1,4,7-triaza-1-cyclononyl)-2-hydroxypropane and Its Stabilization of the Fe4O6 Core," Inorg. Chem. 1993, 32, 4277-4283.

Sessler, J. L.; Sibert, J. W.; Lynch, V.; Markert, J. T.; Wooten, C. L. "Structure and Properties of a Tetranuclear Iron(III) Cage Complex. A Model for Hemerythrin," Inorg. Chem. 1993, 32, 621-626.

Sessler, J. L.; Sibert, J. W.; Lynch, V. "Synthesis and Crystal Structure of the 1:1 Pd(II) Complex of 1,4,7,10-Tetraoxa-13,16,19,22-tetraazacyclotetracosane," Inorg. Chim. Acta 1993, 206, 63-67.

Lynch, V. M.; Sibert, J. W.; Sessler, J. L.; Davis, B. E. "Structure of Aqua-hexakis(μ2-benzoato)-bis(methanol)-μ3-oxo-triiron(III) Benzoate Ethanol Methanol Solvate," Acta Crystallogr. 1991, C47, 866-869.

Sessler, J. L.; Sibert, J. W.; Lynch, V. "Model Studies Related to Hemerythrin. Synthesis and Characterization of a Bridged Tetranuclear Iron(III) Complex," Inorg. Chem. 1990, 29, 4143-4146.

Sessler, J. L.; Sibert, J. W.; Hugdahl, J. D.; Lynch, V. "Synthesis and Characterization of a New Potentially Ditopic Receptor, 1,4,7,10-Tetraoxa-13,16,19,22-tetraazacyclotetracosane, and the X-ray Crystal Structure of Its Mononuclear Copper(II) Complex," Inorg. Chem. 1989, 28, 1417-1419.

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